| Literature DB >> 19766990 |
Ye Cai1, Chang-Chun Ling, David R Bundle.
Abstract
A general and flexible synthetic approach to biologically important 5,6-unsaturated C(18)-phytosphingosines was developed via olefin cross-metathesis employing truncated C(6)-phytosphingosines as the key intermediates. These were efficiently prepared in high yields by zinc-mediated reductive opening of methyl 2-amino-2-deoxy-beta-hexopyranosides. [structure: see text]Entities:
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Year: 2009 PMID： 19766990 DOI： 10.1016/j.carres.2009.07.007
Source DB: PubMed Journal: Carbohydr Res ISSN： 0008-6215 Impact factor: 2.104