Literature DB >> 19764244

Trichloroethylene transformation in aerobic pyrite suspension: pathways and kinetic modeling.

Hoa T Pham1, Koichi Suto, Chihiro Inoue.   

Abstract

The pathways and kinetics of trichloroethylene (TCE) degradation in aerobic pyrite suspension were investigated. The detection of hydroxyl radical in aqueous pyrite suspension suggested that TCE was degraded by this strong oxidant The reaction pathways of TCE degradation were proposed in which the degradation of TCE to formic acid and finally to CO2 was the main route. Degradation of TCE to oxalic acid and to dichloroacetic acid were found as minor pathways. Degradation rates of TCE to formic acid, glyoxylic acid, and dichloroacetic acid were obtained using kinetic model at 1.2 x 10(-2), 9.8 x 10(-4) and 4.6 x 10(-4) h(-1), respectively.

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Year:  2009        PMID: 19764244     DOI: 10.1021/es900623u

Source DB:  PubMed          Journal:  Environ Sci Technol        ISSN: 0013-936X            Impact factor:   9.028


  3 in total

1.  Efficient degradation of TCE in groundwater using Pd and electro-generated H2 and O2: a shift in pathway from hydrodechlorination to oxidation in the presence of ferrous ions.

Authors:  Songhu Yuan; Xuhui Mao; Akram N Alshawabkeh
Journal:  Environ Sci Technol       Date:  2012-03-01       Impact factor: 9.028

2.  Application of ascorbic acid to enhance trichloroethene degradation by Fe(III)-activated calcium peroxide.

Authors:  Xiang Zhang; Xiaogang Gu; Shuguang Lu; Mark L Brusseau; Minhui Xu; Xiaori Fu; Zhaofu Qiu; Qian Sui
Journal:  Chem Eng J       Date:  2017-05-10       Impact factor: 13.273

3.  Phenylalanine as a hydroxyl radical-specific probe in pyrite slurries.

Authors:  Shawn C Fisher; Martin Aa Schoonen; Bruce J Brownawell
Journal:  Geochem Trans       Date:  2012-02-07       Impact factor: 4.737

  3 in total

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