Literature DB >> 19754126

Origin of enantioselectivity in the Jacobsen epoxidation of olefins.

László Kürti1, Megan M Blewett, E J Corey.   

Abstract

It is proposed that facial selectivity in the Jacobsen epoxidation is determined by electrostatic and steric factors with a two-step pathway involving a carbocationic intermediate.

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Year:  2009        PMID： 19754126     DOI： 10.1021/ol901859d

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Aromatic interactions as control elements in stereoselective organic reactions.

Authors:  Elizabeth H Krenske; K N Houk
Journal:  Acc Chem Res       Date:  2012-07-24       Impact factor: 22.384

2.  Mechanism of the enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes.

Authors:  M Kevin Brown; Megan M Blewett; James R Colombe; E J Corey
Journal:  J Am Chem Soc       Date:  2010-08-18       Impact factor: 15.419

3.  Rhodamine B oxidation promoted by P450-bioinspired Jacobsen catalysts/cellulose systems.

Authors:  Lucas Bomfim Bolzon; Anna Karolina Dos Santos Bindeiro; Ana Luiza Marques de Oliveira Souza; Lucas Dimarô Zanatta; Rodrigo de Paula; Bruna Costa Cerqueira; Joicy Santamalvina Dos Santos
Journal:  RSC Adv       Date:  2021-11-02       Impact factor: 3.361
  3 in total

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