| Literature DB >> 19737015 |
Robert V Kolakowski1, Madhuri Manpadi, Yue Zhang, Thomas J Emge, Lawrence J Williams.
Abstract
A new method of allene synthesis is described. Suitably functionalized vinyl triflates undergo fragmentation to give allenes in high yield. Computational and experimental data provide a mechanistic framework for allene formation and the complementary formation of alkynes. The method is stereospecific.Entities:
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Year: 2009 PMID： 19737015 DOI： 10.1021/ja906189h
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419