Literature DB >> 19737012

A bulky bis-pocket manganese(V)-oxo corrole complex: observation of oxygen atom transfer between triply bonded Mn(V)[triple bond]O and alkene.

Hai-Yang Liu1, Fei Yam, Yu-Tao Xie, Xiao-Yuan Li, Chi K Chang.   

Abstract

The highly bulky bis-pocket corrole 5,10,15-tris(2,4,6-triphenylphenyl)corrole (H(3)TTPPC) has been synthesized. Resonance Raman spectroscopy revealed a triply bonded Mn[triple bond]O moiety in its manganese(V)-oxo complex. Direct oxygen atom transfer from (TTPPC)Mn[triple bond]O to styrene was confirmed by an (18)O-labeling experiment. The (TTPPC)Mn(III) complex also exhibits significant shape selectivity in the catalytic epoxidation of nonconjugated dienes.

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Year:  2009        PMID： 19737012     DOI： 10.1021/ja905153r

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  18 in total

1.  Factors Affecting Hydrogen Atom Transfer Reactivity of Metal-Oxo Porphyrinoid Complexes.

Authors:  Jireh Joy D Sacramento; David P Goldberg
Journal:  Acc Chem Res       Date:  2018-11-07       Impact factor: 22.384

2.  Manganese(III) complexes of bis(hydroxyphenyl)dipyrromethenes are potent orally active peroxynitrite scavengers.

Authors:  Smita Rausaria; Andrew Kamadulski; Nigam P Rath; Leesa Bryant; Zhoumou Chen; Daniela Salvemini; William L Neumann
Journal:  J Am Chem Soc       Date:  2011-03-03       Impact factor: 15.419

3.  Reactivity and O2 Formation by Mn(IV)- and Mn(V)-Hydroxo Species Stabilized within a Polyfluoroxometalate Framework.

Authors:  Roy E Schreiber; Hagai Cohen; Gregory Leitus; Sharon G Wolf; Ang Zhou; Lawrence Que; Ronny Neumann
Journal:  J Am Chem Soc       Date:  2015-06-29       Impact factor: 15.419

4.  Direct Observation of Oxygen Rebound with an Iron-Hydroxide Complex.

Authors:  Jan Paulo T Zaragoza; Timothy H Yosca; Maxime A Siegler; Pierre Moënne-Loccoz; Michael T Green; David P Goldberg
Journal:  J Am Chem Soc       Date:  2017-09-20       Impact factor: 15.419

5.  The Selective Monobromination of a Highly Sterically Encumbered Corrole: Structural and Spectroscopic Properties of Fe(Cl)(2-Bromo-5,10,15-tris(triphenyl)phenyl corrole).

Authors:  Jessica G Alvarado; Daniel C Cummins; Andrada Diaconescu; Maxime A Siegler; David P Goldberg
Journal:  J Porphyr Phthalocyanines       Date:  2021       Impact factor: 1.914

6.  Halogen Transfer to Carbon Radicals by High-Valent Iron Chloride and Iron Fluoride Corroles.

Authors:  Geoffrey W Farley; Maxime A Siegler; David P Goldberg
Journal:  Inorg Chem       Date:  2021-10-28       Impact factor: 5.436

7.  A Reactive Manganese(IV)-Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds.

Authors:  Jan Paulo T Zaragoza; Maxime A Siegler; David P Goldberg
Journal:  J Am Chem Soc       Date:  2018-03-15       Impact factor: 15.419

8.  Dioxygen Activation and O-O Bond Formation Reactions by Manganese Corroles.

Authors:  Mian Guo; Yong-Min Lee; Ranjana Gupta; Mi Sook Seo; Takehiro Ohta; Hua-Hua Wang; Hai-Yang Liu; Sunder N Dhuri; Ritimukta Sarangi; Shunichi Fukuzumi; Wonwoo Nam
Journal:  J Am Chem Soc       Date:  2017-10-31       Impact factor: 15.419

9.  Synthesis and photophysical studies of self-assembled multicomponent supramolecular coordination prisms bearing porphyrin faces.

Authors:  Yanhui Shi; Irene Sánchez-Molina; Changsheng Cao; Timothy R Cook; Peter J Stang
Journal:  Proc Natl Acad Sci U S A       Date:  2014-06-16       Impact factor: 11.205

10.  Dramatic influence of an anionic donor on the oxygen-atom transfer reactivity of a Mn(V) -oxo complex.

Authors:  Heather M Neu; Matthew G Quesne; Tzuhsiung Yang; Katharine A Prokop-Prigge; Kyle M Lancaster; James Donohoe; Serena DeBeer; Sam P de Visser; David P Goldberg
Journal:  Chemistry       Date:  2014-09-26       Impact factor: 5.236
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