| Literature DB >> 19736982 |
Tendai Gadzikwa1, Omar K Farha, Christos D Malliakas, Mercouri G Kanatzidis, Joseph T Hupp, SonBinh T Nguyen.
Abstract
A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using "click" chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were "clicked" onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.Entities:
Year: 2009 PMID: 19736982 DOI: 10.1021/ja904189d
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419