Literature DB >> 19719177

Phase-vanishing reactions with PTFE (Teflon) as a phase screen.

Nathan J Van Zee1, Veljko Dragojlovic.   

Abstract

Phase-vanishing reactions are triphasic reactions, which involve a reagent, a liquid perfluoroalkane, and a substrate. In a phase-vanishing reaction with PTFE tape as the phase screen instead of a liquid perfluoroalkane, there is no limitation related to the density of a phase and the denser phase can be in the top layer. The reactions were faster compared to traditional PV reactions, and it was possible to carry out sequential and tandem reactions and reactions under a reflux.

Entities:  

Year:  2009        PMID: 19719177     DOI: 10.1021/ol901450h

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Solvent-free phase-vanishing reactions with PTFE (Teflon®) as a phase screen.

Authors:  Kevin Pels; Veljko Dragojlovic
Journal:  Beilstein J Org Chem       Date:  2009-12-09       Impact factor: 2.883

2.  Properties of PTFE tape as a semipermeable membrane in fluorous reactions.

Authors:  Brendon A Parsons; Olivia Lin Smith; Myeong Chae; Veljko Dragojlovic
Journal:  Beilstein J Org Chem       Date:  2015-06-09       Impact factor: 2.883

  2 in total

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