Thermal-pressure-mediated hydrolysis of Reactive Blue 19 dye.

The thermal-pressure-mediated hydrolysis rates and the degradation kinetics of environmentally persistent Reactive Blue (RB) 19 dye were studied. The dye decomposition was studied at 40-120 degrees C, pH 2-10, and atmospheric pressure range of 1-2 atm. The intermediates and end products formed during the degradation were identified using gas chromatography/mass spectrometry and a possible degradation pathway of RB 19 was proposed. The stability of the dye in aqueous solution was influenced by changes in pH. At pH 4, half-life was 2247.5 min at 40 degrees C and it reduced to 339.4 min when the temperature was increased to 120 degrees C. Acidic conditions were more conducive to enhance hydrolysis rate than basic ones as the decomposition was optimum at pH 4. The kinetic studies indicated that the rate of hydrolysis apparently followed first order reaction. A linear relationship was observed between hydrolysis rate of RB 19 dye and increasing temperatures and pressures. Overall, 23% dye decomposition occurred in 120 minutes at pH 4, 120 degrees C and pressure of 2 atm. Along with thermal-pressure, a combination of techniques like physico-chemical, biological, enzymatic etc. may be more suitable choice for the effective treatment of RB19 dye.