| Literature DB >> 19715289 |
Takeshi Hanamoto1, Kenji Yamada.
Abstract
The reaction of (trifluoromethyl)dimethylphenylsilylacetylene and (eta(2)-propene)Ti(O(i)Pr)(2) generated in situ smoothly proceeded giving the corresponding (eta(2)-1-dimethylphenylsilyl-2-trifluoromethylalkyne)Ti(O(i)Pr)(2), which reacted with aldehydes and ketones to afford the corresponding addition products in good yields with good to excellent regioselectivity.Entities:
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Year: 2009 PMID： 19715289 DOI： 10.1021/jo901392n
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354