| Literature DB >> 19673513 |
Eugenia Marqués-López1, Raquel P Herrera, Timo Marks, Wiebke C Jacobs, Daniel Könning, Renata M de Figueiredo, Mathias Christmann.
Abstract
The intramolecular Rauhut-Currier reaction creates a carbon-carbon bond between two tethered Michael acceptors. Previous asymmetric versions have relied on 1,4-additions of chiral nucleophilic catalysts. Herein, we investigate a novel strategy that involves the formation of electron rich dienamines as key intermediates. Our methodology provides an efficient entry to the iridoid framework.Entities:
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Year: 2009 PMID： 19673513 DOI： 10.1021/ol901614t
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005