Characterization of particle bound organic carbon from diesel vehicles equipped with advanced emission control technologies.

A chassis dynamometer study was carried out by the University of Southern California in collaboration with the Air Resources Board (CARB) to investigate the physical, chemical, and toxicological characteristics of diesel emissions of particulate matter (PM) from heavy-duty vehicles. These heavy-duty diesel vehicles (HDDV) were equipped with advanced emission control technologies, designed to meet CARB retrofit regulations. A HDDV without any emission control devices was used as the baseline vehicle. Three advanced emission control technologies; continuously regenerating technology (CRT), zeolite- and vanadium-based selective catalytic reduction technologies (Z-SCRT and V-SCRT), were tested under transient (UDDS) (1) and cruise (80 kmph) driving cycles to simulate real-world driving conditions. This paper focuses on the characterization of the particle bound organic species from the vehicle exhaust. Physical and chemical properties of PM emissions have been reported by Biswas et al. Atmos. Environ. 2008, 42, 5622-5634) and Hu et al. (Atmos. Environ. 2008, submitted) Significant reductions in the emission factors (microg/mile) of particle bound organic compounds were observed in HDDV equipped with advanced emission control technologies. V-SCRT and Z-SCRT effectively reduced PAHs, hopanes and steranes, n-alkanes and acids by more than 99%, and often to levels below detection limits for both cruise and UDDS cycles. The CRT technology also showed similar reductions with SCRT for medium and high molecular weight PAHs, acids, but with slightly lower removal efficiencies for other organic compounds. Ratios of particle bound organics-to-OC mass (microg/g) from the baseline exhaust were compared with their respective ratios in diesel fuel and lubricating oil, which revealed that hopanes and steranes originate from lubricating oil, whereas PAHs can either form during the combustion process or originate from diesel fuel itself. With the introduction of emission control technologies, the particle bound organics-to-OC ratios (microg/g) decreased considerably for PAHs, while the reduction was insignificant for hopanes and steranes, implying that fuel and lubricating oil have substantially different contributions to the total OC emitted by vehicles operating with after-treatment control devices compared to the baseline vehicle since these control technologies had a much larger impact on PAH OC than hopanes and steranes OC.