Literature DB >> 19668811

Chemoselective hydroboration of alkynes vs. alkenes over gold catalysts.

Antonio Leyva1, Xin Zhang, Avelino Corma.   

Abstract

Alkynes are preferentially hydroborated in the presence of alkenes when using gold catalysts; the active species involves a borane-gold interaction.

Entities:  

Year:  2009        PMID: 19668811     DOI: 10.1039/b901953g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Alkene hydroboration with pinacolborane catalysed by lithium diisobutyl-tert-butoxyaluminum hydride.

Authors:  Ashok Kumar Jaladi; Won Kyu Shin; Duk Keun An
Journal:  RSC Adv       Date:  2019-08-23       Impact factor: 3.361

2.  Copper-Catalyzed Triboration of Terminal Alkynes Using B2 pin2 : Efficient Synthesis of 1,1,2-Triborylalkenes.

Authors:  Xiaocui Liu; Wenbo Ming; Alexandra Friedrich; Florian Kerner; Todd B Marder
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-19       Impact factor: 15.336

  2 in total

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