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Literature DB >> 19662295

Synthesis, characterization and structure of a low coordinate desoxomolybdenum cluster stabilized by a dithione ligand.

Abstract

Using an oxidized state of a dithiolene ligand, n class="Chemical">diisopropylpiperazine-2,3-dithione (i-Pr(2)Pipdt), two monooxo-molybdenum complexes have been synthesized. From one of them, a desoxomolybdenum cluster, [(i-Pr(2)Pipdt)Mo](4)[BF(4)](4) has been prepared. The molecular structure of this cluster reveals metal-metal interactions and weak coordination by the BF(4) anion.

Entities: Chemical Disease Mutation Species

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Year: 2009 PMID： 19662295 PMCID： PMC2894468 DOI： 10.1039/b904113c

Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390

14 in total

1. The lengths of molybdenum to molybdenum quadruple bonds: correlations, explanations, and corrections.

Authors: F Albert Cotton; Lee M Daniels; Elizabeth A Hillard; Carlos A Murillo
Journal: Inorg Chem Date: 2002-05-06 Impact factor: 5.165

2. Synthesis, molecular and electronic structure, and TDDFT and TDDFT-PCM study of the solvatochromic properties of (Me2Pipdt)Mo(CO)4 complex (Me2Pipdt = N,N'-dimethylpiperazine-2,3-dithione).

Authors: Victor N Nemykin; Joseph G Olsen; Eranda Perera; Partha Basu
Journal: Inorg Chem Date: 2006-05-01 Impact factor: 5.165

Review 3. Synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases.

Authors: John H Enemark; J Jon A Cooney; Jun-Jieh Wang; R H Holm
Journal: Chem Rev Date: 2004-02 Impact factor: 60.622

4. Conducting metal dithiolene complexes: structural and electronic properties.

Authors: Reizo Kato
Journal: Chem Rev Date: 2004-11 Impact factor: 60.622

5. Rotational barrier of a molybdenum-molybdenum quadruple bond.

Authors: J P Collman; L K Woo
Journal: Proc Natl Acad Sci U S A Date: 1984-04 Impact factor: 11.205

6. Proton induced P-H and Mo-H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(mu-H)(mu-PHR)(CO)4](R = Cy, 2,4,6-C6H2R'3; R'= H, Me, tBu).

Authors: Celedonio M Alvarez; M Angeles Alvarez; Daniel García-Vivó; M Esther García; Miguel A Ruiz; David Saáez; Larry R Falvello; Tatiana Soler; Patrick Herson
Journal: Dalton Trans Date: 2004-11-15 Impact factor: 4.390

7. A bifurcated pathway of oxygen atom transfer reactions from a monooxo molybdenum(VI) complex under electrospray ionisation mass spectrometric conditions.

Authors: Victor N Nemykin; Partha Basu
Journal: Dalton Trans Date: 2004-06-01 Impact factor: 4.390

8. Mono-oxo bis(dithiolene) Mo(IV)/W(IV) complexes as building blocks for sulfide bridged Bi- and Tri-nuclear complexes.

Authors: Amit Majumdar; Joyee Mitra; Kuntal Pal; Sabyasachi Sarkar
Journal: Inorg Chem Date: 2008-05-10 Impact factor: 5.165

9. Electronic factors affecting second-order NLO properties: case study of four different push-pull bis-dithiolene nickel complexes.

Authors: Simona Curreli; Paola Deplano; Christophe Faulmann; Andrea Ienco; Carlo Mealli; Maria Laura Mercuri; Luca Pilia; Gloria Pintus; Angela Serpe; Emanuele F Trogu
Journal: Inorg Chem Date: 2004-08-09 Impact factor: 5.165

10. Heterospin systems constructed from [Cu2Ln]3+ and [Ni(mnt)2]1-,2- Tectons: First 3p-3d-4f complexes (mnt = maleonitriledithiolato).

Authors: Augustin M Madalan; Narcis Avarvari; Marc Fourmigué; Rodolphe Clérac; Liviu F Chibotaru; Sergiu Clima; Marius Andruh
Journal: Inorg Chem Date: 2008-01-03 Impact factor: 5.165

8 in total

Synthesis, characterization and structure of a low coordinate desoxomolybdenum cluster stabilized by a dithione ligand.

1. The lengths of molybdenum to molybdenum quadruple bonds: correlations, explanations, and corrections.

2. Synthesis, molecular and electronic structure, and TDDFT and TDDFT-PCM study of the solvatochromic properties of (Me2Pipdt)Mo(CO)4 complex (Me2Pipdt = N,N'-dimethylpiperazine-2,3-dithione).

Review 3. Synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases.

4. Conducting metal dithiolene complexes: structural and electronic properties.

5. Rotational barrier of a molybdenum-molybdenum quadruple bond.

6. Proton induced P-H and Mo-H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(mu-H)(mu-PHR)(CO)4](R = Cy, 2,4,6-C6H2R'3; R'= H, Me, tBu).

7. A bifurcated pathway of oxygen atom transfer reactions from a monooxo molybdenum(VI) complex under electrospray ionisation mass spectrometric conditions.

8. Mono-oxo bis(dithiolene) Mo(IV)/W(IV) complexes as building blocks for sulfide bridged Bi- and Tri-nuclear complexes.

9. Electronic factors affecting second-order NLO properties: case study of four different push-pull bis-dithiolene nickel complexes.

10. Heterospin systems constructed from [Cu2Ln]3+ and [Ni(mnt)2]1-,2- Tectons: First 3p-3d-4f complexes (mnt = maleonitriledithiolato).

1. Large Ligand Folding Distortion in an Oxomolybdenum Donor-Acceptor Complex.

2. A Valence Bond Description of Dizwitterionic Dithiolene Character in an Oxomolybdenum-bis(dithione).

3. Recent developments in the study of molybdoenzyme models.

4. Dithiolopyranthione Synthesis, Spectroscopy and an Unusual Reactivity with DDQ.

5. Solution, Solid, and Gas Phase Studies on a Nickel Dithiolene System: Spectator Metal and Reactor Ligand.

Review 6. Nitrate and periplasmic nitrate reductases.

7. Syntheses, spectroscopic, redox, and structural properties of homoleptic Iron(III/II) dithione complexes.

8. Interligand communication in a metal mediated LL'CT system - a case study.