Literature DB >> 19662263

The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar = 3,5-(CF(3))(2)C(6)H(3)).

Simone Fantauzzi1, Emma Gallo, Alessandro Caselli, Fabio Ragaini, Nicola Casati, Piero Macchi, Sergio Cenini.   

Abstract

The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.

Entities:  

Year:  2009        PMID： 19662263     DOI： 10.1039/b903238j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  12 in total

1.  Ruthenium-catalyzed γ-carbolinium ion formation from aryl azides; synthesis of dimebolin.

Authors:  Huijun Dong; Regina T Latka; Tom G Driver
Journal:  Org Lett       Date:  2011-04-25       Impact factor: 6.005

2.  Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions.

Authors:  Monalisa Goswami; Volodymyr Lyaskovskyy; Sérgio R Domingos; Wybren Jan Buma; Sander Woutersen; Oliver Troeppner; Ivana Ivanović-Burmazović; Hongjian Lu; Xin Cui; X Peter Zhang; Edward J Reijerse; Serena DeBeer; Matti M van Schooneveld; Florian Felix Pfaff; Kallol Ray; Bas de Bruin
Journal:  J Am Chem Soc       Date:  2015-04-16       Impact factor: 15.419

3.  Recent advances in transition metal-catalyzed N-atom transfer reactions of azides.

Authors:  Tom G Driver
Journal:  Org Biomol Chem       Date:  2010-07-08       Impact factor: 3.876

4.  Inverting Steric Effects: Using "Attractive" Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer.

Authors:  Minxue Huang; Tzuhsiung Yang; Jonathan D Paretsky; John F Berry; Jennifer M Schomaker
Journal:  J Am Chem Soc       Date:  2017-11-20       Impact factor: 15.419

5.  Rh2(II)-Catalyzed Intermolecular N-Aryl Aziridination of Olefins Using Nonactivated N Atom Precursors.

Authors:  Tianning Deng; Wrickban Mazumdar; Yuki Yoshinaga; Pooja B Patel; Dana Malo; Tala Malo; Donald J Wink; Tom G Driver
Journal:  J Am Chem Soc       Date:  2021-11-08       Impact factor: 15.419

6.  Rhodium-catalyzed synthesis of 2,3-disubstituted indoles from β,β-disubstituted stryryl azides.

Authors:  Ke Sun; Sheng Liu; Patryk M Bec; Tom G Driver
Journal:  Angew Chem Int Ed Engl       Date:  2011-01-14       Impact factor: 15.336

7.  P450-catalyzed intramolecular sp3 C-H amination with arylsulfonyl azide substrates.

Authors:  Ritesh Singh; Melanie Bordeaux; Rudi Fasan
Journal:  ACS Catal       Date:  2014-01-06       Impact factor: 13.084

8.  Enzymatic C(sp3)-H Amination: P450-Catalyzed Conversion of Carbonazidates into Oxazolidinones.

Authors:  Ritesh Singh; Joshua N Kolev; Philip A Sutera; Rudi Fasan
Journal:  ACS Catal       Date:  2015-01-29       Impact factor: 13.084

9.  In situ generation of N-unsubstituted imines from alkyl azides and their applications for imine transfer via copper catalysis.

Authors:  Lu Hu; Yahu A Liu; Xuebin Liao
Journal:  Sci Adv       Date:  2017-08-09       Impact factor: 14.136

10.  Cobalt-Porphyrin-Catalysed Intramolecular Ring-Closing C-H Amination of Aliphatic Azides: A Nitrene-Radical Approach to Saturated Heterocycles.

Authors:  Petrus F Kuijpers; Martijn J Tiekink; Willem B Breukelaar; Daniël L J Broere; Nicolaas P van Leest; Jarl Ivar van der Vlugt; Joost N H Reek; Bas de Bruin
Journal:  Chemistry       Date:  2017-05-02       Impact factor: 5.236
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