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Literature DB >> 19662238

Synthesis and structural characterisation of stable cationic gold(I) alkene complexes.

Thomas N Hooper¹, Michael Green, John E McGrady, Jaynika R Patel, Christopher A Russell.

Abstract

Treatment of [AuCl(PBu(t)(3))] with AgSbF(6) in CH(2)Cl(2) at room temperature in the presence of the alkenes norbornene, norbornadiene, trans-cyclooctene, and also interestingly, isobutylene, leads to the formation of stable crystalline complexes [Au(PBu(t)(3))(alkene)][SbF(6)], characterised by NMR spectroscopy and X-ray crystallography.

Entities: Chemical

Year: 2009 PMID： 19662238 DOI： 10.1039/b908109g

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

12 in total

1. Alkylgold complexes by the intramolecular aminoauration of unactivated alkenes.

Authors: Rebecca L Lalonde; William E Brenzovich; Diego Benitez; Ekaterina Tkatchouk; Kotaro Kelley; William A Goddard; F Dean Toste
Journal: Chem Sci Date: 2010-08-01 Impact factor: 9.825

2. Gold(I)-Catalyzed Intramolecular Hydroamination of N-Allylic,N'-Aryl Ureas to form Imidazolidin-2-ones.

Authors: Hao Li; Feijie Song; Ross A Widenhoefer
Journal: Adv Synth Catal Date: 2011-04-18 Impact factor: 5.837

3. Gold(I)-catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles.

Authors: Paramita Mukherjee; Ross A Widenhoefer
Journal: Org Lett Date: 2010-03-19 Impact factor: 6.005

4. Gold(I)-catalyzed intramolecular amination of allylic alcohols with alkylamines.

Authors: Paramita Mukherjee; Ross A Widenhoefer
Journal: Org Lett Date: 2011-02-11 Impact factor: 6.005

Review 5. Stable cyclic carbenes and related species beyond diaminocarbenes.

Authors: Mohand Melaimi; Michèle Soleilhavoup; Guy Bertrand
Journal: Angew Chem Int Ed Engl Date: 2010-11-15 Impact factor: 15.336

6. Revisiting the Bonding Model for Gold(I) Species: The Importance of Pauli Repulsion Revealed in a Gold(I)-Cyclobutadiene Complex.

Authors: Zeng Rong Wong; Tim K Schramm; Matthias Loipersberger; Martin Head-Gordon; F Dean Toste
Journal: Angew Chem Int Ed Engl Date: 2022-03-30 Impact factor: 16.823

Synthesis and structural characterisation of stable cationic gold(I) alkene complexes.

1. Alkylgold complexes by the intramolecular aminoauration of unactivated alkenes.

2. Gold(I)-Catalyzed Intramolecular Hydroamination of N-Allylic,N'-Aryl Ureas to form Imidazolidin-2-ones.

3. Gold(I)-catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles.

4. Gold(I)-catalyzed intramolecular amination of allylic alcohols with alkylamines.

Review 5. Stable cyclic carbenes and related species beyond diaminocarbenes.

6. Revisiting the Bonding Model for Gold(I) Species: The Importance of Pauli Repulsion Revealed in a Gold(I)-Cyclobutadiene Complex.

7. Synthesis and equilibrium binding studies of cationic, two-coordinate gold(I) π-alkyne complexes.

8. Versatility and adaptative behaviour of the P^N chelating ligand MeDalphos within gold(i) π complexes.

9. Gold(I) and Silver(I) π-Complexes with Unsaturated Hydrocarbons.

10. Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.