| Literature DB >> 19655754 |
Hiroyoshi Takamura1, Takeshi Murata, Takahiro Asai, Isao Kadota, Daisuke Uemura.
Abstract
Stereoselective synthesis of the C1'-C25' fragment of symbiodinolide, which was obtained as a degraded product from symbiodinolide by alkaline hydrolysis, has been accomplished. The synthetic route features Kotsuki coupling and Julia-Kocienski olefination in the introduction of the side chains. This enantio- and stereoselective synthesis has established the absolute configuration of the C1'-C25' fragment.Entities:
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Year: 2009 PMID： 19655754 DOI： 10.1021/jo901162v
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354