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Literature DB >> 19652795

Strong magnetic exchange coupling in the cyano-bridged coordination clusters [(PY5Me2)4V4M(CN)6]5+ (M = Cr, Mo).

Danna E Freedman¹, David M Jenkins, Jeffrey R Long.

Abstract

Reaction of [(PY5Me2)V(MeCN)]2+ with [M(CN)6]3- (M = Cr, Mo) affords the star-like clusters [(PY5Me2)4V4M(CN)6]5+, exhibiting S = 9/2 ground states that are exceptionally well-isolated in energy.

Entities: Chemical

Year: 2009 PMID： 19652795 DOI： 10.1039/b908736b

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

1 in total

1. Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru^II complexes: comparison to bimetallic analogs.

Authors: Sungho V Park; John F Berry
Journal: Dalton Trans Date: 2017-07-18 Impact factor: 4.390

1 in total

Strong magnetic exchange coupling in the cyano-bridged coordination clusters [(PY5Me2)4V4M(CN)6]5+ (M = Cr, Mo).

1. Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported RuII complexes: comparison to bimetallic analogs.

1. Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru^II complexes: comparison to bimetallic analogs.