Literature DB >> 19652313

catena-Poly[[bis(acetylacetonato-kappa2O,O')cobalt(II)]-mu-1,3-di-4-pyridylpropane-kappa2N:N']: a one-dimensional coordination polymer capable of forming clathrates with prochiral aldehydes.

Anders Lennartson1, Mikael Håkansson.   

Abstract

The title compound, [Co(C5H7O2)2(C13H14N2)]n, forms a coordination polymer in which the Co(II) centre is located on an inversion centre and the 1,3-di-4-pyridylpropane ligand is located on a twofold axis. The polymeric chains are parallel and are held together by weak intermolecular C-H...O interactions. The complex is intended as a possible host for prochiral aldehydes and ketones, and one clathrate was isolated with p-tolylaldehyde.

Entities:  

Year:  2009        PMID: 19652313     DOI: 10.1107/S0108270109027589

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Orientational disorder in the one-dimensional coordination polymer catena-poly[[bis-(acetyl-acetonato-κ(2) O,O')cobalt(II)]-μ-1,4-di-aza-bicyclo-[2.2.2]octane-κ(2) N (1):N (4)].

Authors:  Florina Dumitru; Ulli Englert; Beatrice Braun
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-03-31
  1 in total

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