Literature DB >> 19650627

A superior precursor for palladium(0)-based cross-coupling and other catalytic reactions.

Danielle M Norton1, Emily A Mitchell, Nerine R Botros, Philip G Jessop, Michael C Baird.   

Abstract

The easily synthesized, easily handled compound Pd(eta(3)-1-PhC(3)H(4))(eta(5)-C(5)H(5)) (II) reacts readily with mono- and bidentate tertiary phosphines to produce the corresponding bis-phosphine palladium(0) complexes in good yields; II is thus an excellent precursor, perhaps the most efficacious and reliable available, for the synthesis of palladium(0) cross-coupling catalysts.

Entities:  

Year:  2009        PMID： 19650627     DOI： 10.1021/jo901121e

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Mechanistic Studies of the Palladium-Catalyzed Desulfinative Cross-Coupling of Aryl Bromides and (Hetero)Aryl Sulfinate Salts.

Authors:  Antoine de Gombert; Alasdair I McKay; Christopher J Davis; Katherine M Wheelhouse; Michael C Willis
Journal:  J Am Chem Soc       Date:  2020-02-07       Impact factor: 15.419

2.  Comparison of the catalytic activity for the Suzuki-Miyaura reaction of (η(5)-Cp)Pd(IPr)Cl with (η(3)-cinnamyl)Pd(IPr)(Cl) and (η(3)-1-t-Bu-indenyl)Pd(IPr)(Cl).

Authors:  Patrick R Melvin; Nilay Hazari; Hannah M C Lant; Ian L Peczak; Hemali P Shah
Journal:  Beilstein J Org Chem       Date:  2015-12-08       Impact factor: 2.883

3.  Palladium-catalyzed regioselective and stereo-invertive ring-opening borylation of 2-arylaziridines with bis(pinacolato)diboron: experimental and computational studies.

Authors:  Youhei Takeda; Akinobu Kuroda; W M C Sameera; Keiji Morokuma; Satoshi Minakata
Journal:  Chem Sci       Date:  2016-06-09       Impact factor: 9.825
  3 in total

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