Literature DB >> 19637862

Zirconium-mediated coupling reaction for synthesis of substituted thiophene-fused acenes.

Yang Ni1, Kiyohiko Nakajima, Ken-ichiro Kanno, Tamotsu Takahashi.   

Abstract

A novel zirconium-mediated synthesis of substituted thiophene-fused acenes is described. A variety of substituents, such as alkyl, aryl, silyl, iodo, and alkynyl groups, could be introduced to the acene skeleton by this method. Moreover, the double coupling with tetraiodothiophene gave the corresponding dianthrathiophene.

Entities:  

Year:  2009        PMID: 19637862     DOI: 10.1021/ol900903w

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  A one-pot successive cyclization-alkylation strategy for the synthesis of 2,3-disubstituted benzo[b]thiophenes.

Authors:  Christopher Cunningham; Matthew Cloyd; Aimee Phillips; Soha Khan; Katherine Whalen; Tanay Kesharwani
Journal:  Org Biomol Chem       Date:  2021-05-12       Impact factor: 3.876

  1 in total

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