Literature DB >> 19630397

Stereoselective synthesis of alpha-alkyl-beta-keto imides via asymmetric redox C-C bond formation between alpha-alkyl-alpha-diazocarbonyl compounds and aldehydes.

Takuya Hashimoto1, Hisashi Miyamoto, Yuki Naganawa, Keiji Maruoka.   

Abstract

Asymmetric redox C-C bond formation between alpha-alkyl-alpha-diazocarbonyl compounds and aldehydes was developed as a practical and general method for the construction of alpha-alkyl-beta-keto imides having a chiral nonracemic tertiary stereogenic center.

Entities:  

Year:  2009        PMID： 19630397     DOI： 10.1021/ja903500w

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

Review 1.  Acyclic Twisted Amides.

Authors:  Guangrong Meng; Jin Zhang; Michal Szostak
Journal:  Chem Rev       Date:  2021-08-18       Impact factor: 72.087

2.  Modular Synthesis of Cyclopropane-Fused N-Heterocycles Enabled by Underexplored Diazo Reagents.

Authors:  Matthieu J R Richter; Frédéric J Zécri; Karin Briner; Stuart L Schreiber
Journal:  Angew Chem Int Ed Engl       Date:  2022-04-25       Impact factor: 16.823

3.  BOROX catalysis: self-assembled amino-BOROX and imino-BOROX chiral Brønsted acids in a five component catalyst assembly/catalytic asymmetric aziridination.

Authors:  Anil K Gupta; Munmun Mukherjee; Gang Hu; William D Wulff
Journal:  J Org Chem       Date:  2012-09-04       Impact factor: 4.354
  3 in total

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