Literature DB >> 19627106

Carbolithiation of conjugated enynes with aryllithiums in microflow system and applications to synthesis of allenylsilanes.

Yutaka Tomida1, Aiichiro Nagaki, Jun-ichi Yoshida.   

Abstract

Carbolithiation of conjugated enynes with aryllithiums generated by Br-Li exchange reaction followed by reaction of the allenyllithium compounds with chlorosilanes was carried out in a microflow system to obtain various allenylsilanes in good yields.

Entities:  

Year:  2009        PMID： 19627106     DOI： 10.1021/ol901352t

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

Review 1.  Regio- and stereoselective intermolecular carbolithiation reactions.

Authors:  G Marsico; P Scafato; S Belviso; S Superchi
Journal:  RSC Adv       Date:  2020-09-02       Impact factor: 4.036

2.  Homocoupling of aryl halides in flow: Space integration of lithiation and FeCl(3) promoted homocoupling.

Authors:  Aiichiro Nagaki; Yuki Uesugi; Yutaka Tomida; Jun-Ichi Yoshida
Journal:  Beilstein J Org Chem       Date:  2011-08-02       Impact factor: 2.883

3.  Inter- and intramolecular enantioselective carbolithiation reactions.

Authors:  Asier Gómez-Sanjuan; Nuria Sotomayor; Esther Lete
Journal:  Beilstein J Org Chem       Date:  2013-02-13       Impact factor: 2.883
  3 in total

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