Literature DB >> 19623381

Mechanisms of C-H bond activation: rich synergy between computation and experiment.

Youcef Boutadla1, David L Davies, Stuart A Macgregor, Amalia I Poblador-Bahamonde.   

Abstract

Recent computational studies of C-H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom co-ligands or carboxylates are highlighted as a particularly promising means of cleaving C-H bonds. The term 'ambiphilic metal ligand activation' (AMLA) is introduced to describe such reactions.

Entities:  

Year:  2009        PMID： 19623381     DOI： 10.1039/b904967c

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  24 in total

1.  Base-Assisted C-H Bond Cleavage in Cross-Coupling: Recent Insights into Mechanism, Speciation, and Cooperativity.

Authors:  Brad P Carrow; Jessica Sampson; Long Wang
Journal:  Isr J Chem       Date:  2019-12-13       Impact factor: 3.333

2.  Bond-weakening catalysis: conjugate aminations enabled by the soft homolysis of strong N-H bonds.

Authors:  Kyle T Tarantino; David C Miller; Ted A Callon; Robert R Knowles
Journal:  J Am Chem Soc       Date:  2015-05-13       Impact factor: 15.419

3.  Decomposition pathways of Z-selective ruthenium metathesis catalysts.

Authors:  Myles B Herbert; Yu Lan; Benjamin K Keitz; Peng Liu; Koji Endo; Michael W Day; K N Houk; Robert H Grubbs
Journal:  J Am Chem Soc       Date:  2012-04-26       Impact factor: 15.419

Review 4.  If C-H bonds could talk: selective C-H bond oxidation.

Authors:  Timothy Newhouse; Phil S Baran
Journal:  Angew Chem Int Ed Engl       Date:  2011-03-16       Impact factor: 15.336

5.  Synthesis and coordination chemistry of tri-substituted benzamidrazones.

Authors:  Mark R Crimmin; Denise A Colby; Jonathan A Ellman; Robert G Bergman
Journal:  Dalton Trans       Date:  2010-11-25       Impact factor: 4.390

6.  C-H Activation by Isolable Cationic Bis(phosphine) Cobalt(III) Metallacycles.

Authors:  William G Whitehurst; Junho Kim; Stefan G Koenig; Paul J Chirik
Journal:  J Am Chem Soc       Date:  2022-10-04       Impact factor: 16.383

7.  From Pd(OAc)2 to Chiral Catalysts: The Discovery and Development of Bifunctional Mono-N-Protected Amino Acid Ligands for Diverse C-H Functionalization Reactions.

Authors:  Qian Shao; Kevin Wu; Zhe Zhuang; Shaoqun Qian; Jin-Quan Yu
Journal:  Acc Chem Res       Date:  2020-03-31       Impact factor: 22.384

Review 8.  A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors:  Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal:  Chem Soc Rev       Date:  2018-08-28       Impact factor: 54.564

9.  Cobalt-catalysed site-selective intra- and intermolecular dehydrogenative amination of unactivated sp(3) carbons.

Authors:  Xuesong Wu; Ke Yang; Yan Zhao; Hao Sun; Guigen Li; Haibo Ge
Journal:  Nat Commun       Date:  2015-03-10       Impact factor: 14.919

10.  Copper-catalyzed CuAAC/intramolecular C-H arylation sequence: Synthesis of annulated 1,2,3-triazoles.

Authors:  Rajkumar Jeyachandran; Harish Kumar Potukuchi; Lutz Ackermann
Journal:  Beilstein J Org Chem       Date:  2012-10-16       Impact factor: 2.883
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