Literature DB >> 19593753

Gold-catalyzed aerobic oxidation of 5-hydroxymethylfurfural in water at ambient temperature.

Yury Y Gorbanev1, Søren K Klitgaard, John M Woodley, Claus H Christensen, Anders Riisager.   

Abstract

The aerobic oxidation of 5-hydroxymethylfurfural, a versatile biomass-derived chemical, is examined in water with a titania-supported gold-nanoparticle catalyst at ambient temperature (30 °C). The selectivity of the reaction towards 2,5-furandicarboxylic acid and the intermediate oxidation product 5-hydroxymethyl-2-furancarboxylic acid is found to depend on the amount of added base and the oxygen pressure, suggesting that the reaction proceeds via initial oxidation of the aldehyde moiety followed by oxidation of the hydroxymethyl group of 5-hydroxymethylfurfural. Under optimized reaction conditions, a 71% yield of 2,5-furandicarboxylic acid is obtained at full 5-hydroxymethylfurfural conversion in the presence of excess base.
Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2009        PMID： 19593753     DOI： 10.1002/cssc.200900059

Source DB:  PubMed          Journal:  ChemSusChem        ISSN： 1864-5631            Impact factor:   8.928


  10 in total

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Review 2.  Efficient conversion of 5-hydroxymethylfurfural to high-value chemicals by chemo- and bio-catalysis.

Authors:  Haian Xia; Siquan Xu; Hong Hu; Jiahuan An; Changzhi Li
Journal:  RSC Adv       Date:  2018-09-03       Impact factor: 4.036

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Journal:  Chem Sci       Date:  2015-06-08       Impact factor: 9.825

4.  Direct Catalytic Route to Biomass-Derived 2,5-Furandicarboxylic Acid and Its Use as Monomer in a Multicomponent Polymerization.

Authors:  Oliver R Schade; Patrick-Kurt Dannecker; Kai F Kalz; David Steinbach; Michael A R Meier; Jan-Dierk Grunwaldt
Journal:  ACS Omega       Date:  2019-10-01

5.  Oxidative Esterification of 5-Hydroxymethylfurfural into Dimethyl 2,5-Furandicarboxylate Using Gamma Alumina-Supported Gold Nanoparticles.

Authors:  Helapiyumi Weerathunga; Sarina Sarina; Huai-Yong Zhu; Eric R Waclawik
Journal:  ACS Omega       Date:  2021-02-10

6.  Anaerobic oxidation of aldehydes to carboxylic acids under hydrothermal conditions.

Authors:  Yiju Liao; Alexandria Aspin; Ziming Yang
Journal:  RSC Adv       Date:  2022-01-11       Impact factor: 3.361

7.  Porous nitrogen-enriched carbonaceous material from marine waste: chitosan-derived carbon nitride catalyst for aerial oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid.

Authors:  Sanny Verma; Mallikarjuna N Nadagouda; Rajender S Varma
Journal:  Sci Rep       Date:  2017-10-19       Impact factor: 4.379

8.  Colloidal Au Catalyst Preparation: Selective Removal of Polyvinylpyrrolidone from Active Au Sites.

Authors:  Baira Donoeva; Petra E de Jongh
Journal:  ChemCatChem       Date:  2018-02-06       Impact factor: 5.686

9.  Selective Oxidation of HMF via Catalytic and Photocatalytic Processes Using Metal-Supported Catalysts.

Authors:  Alice Lolli; Valeriia Maslova; Danilo Bonincontro; Francesco Basile; Simona Ortelli; Stefania Albonetti
Journal:  Molecules       Date:  2018-10-27       Impact factor: 4.411

10.  Enzymatic conversion reactions of 5-hydroxymethylfurfural (HMF) to bio-based 2,5-diformylfuran (DFF) and 2,5-furandicarboxylic acid (FDCA) with air: mechanisms, pathways and synthesis selectivity.

Authors:  Miša Mojca Cajnko; Uroš Novak; Miha Grilc; Blaž Likozar
Journal:  Biotechnol Biofuels       Date:  2020-04-10       Impact factor: 6.040
  10 in total

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