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Literature DB >> 19588964

Reconstruction of Cu(100) electrode surfaces during hydrogen evolution.

Hisayoshi Matsushima¹, Andriy Taranovskyy, Christian Haak, Yvonne Gründer, Olaf M Magnussen.

Abstract

Electrochemical hydrogen evolution on (100)-oriented copper electrodes is shown to induce a novel surface reconstruction, which substantially influences the rates of this electrochemical reaction. As revealed by in situ video-STM the formation of this phase starts with lateral displacements of Cu surface atoms from lattice positions, resulting in stripe-like structures, followed by expansion of the surface lattice along the stripe direction.

Entities: Chemical Gene

Year: 2009 PMID： 19588964 DOI： 10.1021/ja904033t

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

6 in total

1. Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K.

Authors: Tao Cheng; Hai Xiao; William A Goddard
Journal: Proc Natl Acad Sci U S A Date: 2017-02-06 Impact factor: 11.205

Reconstruction of Cu(100) electrode surfaces during hydrogen evolution.

1. Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K.

2. Understanding trends in electrochemical carbon dioxide reduction rates.

3. Hydrogen-Induced Step-Edge Roughening of Platinum Electrode Surfaces.

4. The Potential of Zero Charge and the Electrochemical Interface Structure of Cu(111) in Alkaline Solutions.

5. Self-organized and cu-coordinated surface linear polymerization.

6. Potential-induced nanoclustering of metallic catalysts during electrochemical CO₂ reduction.

Reconstruction of Cu(100) electrode surfaces during hydrogen evolution.

1. Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K.

2. Understanding trends in electrochemical carbon dioxide reduction rates.

3. Hydrogen-Induced Step-Edge Roughening of Platinum Electrode Surfaces.

4. The Potential of Zero Charge and the Electrochemical Interface Structure of Cu(111) in Alkaline Solutions.

5. Self-organized and cu-coordinated surface linear polymerization.

6. Potential-induced nanoclustering of metallic catalysts during electrochemical CO2 reduction.

6. Potential-induced nanoclustering of metallic catalysts during electrochemical CO₂ reduction.