Literature DB >> 19585990

A Crystallizable dinuclear tuck-in-tuck-over tuck-over dialkyl Tren uranium complex and double dearylation of BPh(4)(-) to give the BPh(2)-functionalized metallocycle [U{N(CH(2)CH(2)NSiMe(3))(2)(CH(2)CH(2)NSiMe(2)CHBPh(2))}(THF)].

Benedict M Gardner1, Jonathan McMaster, William Lewis, Alexander J Blake, Stephen T Liddle.   

Abstract

The unprecedented formation of a dinuclear tuck-in-tuck-over tuck-over dialkyl Tren-uranium(IV) complex and the first example of double dearylation of BPh(4)(-) in a molecular context to give a BPh(2)-functionalized uranium metallocycle are reported.

Entities:  

Year:  2009        PMID： 19585990     DOI： 10.1021/ja904459q

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

1.  Uranium azide photolysis results in C-H bond activation and provides evidence for a terminal uranium nitride.

Authors:  Robert K Thomson; Thibault Cantat; Brian L Scott; David E Morris; Enrique R Batista; Jaqueline L Kiplinger
Journal:  Nat Chem       Date:  2010-07-11       Impact factor: 24.427

2.  Homologation and functionalization of carbon monoxide by a recyclable uranium complex.

Authors:  Benedict M Gardner; John C Stewart; Adrienne L Davis; Jonathan McMaster; William Lewis; Alexander J Blake; Stephen T Liddle
Journal:  Proc Natl Acad Sci U S A       Date:  2012-05-31       Impact factor: 11.205

3.  Nitrogen activation and cleavage by a multimetallic uranium complex.

Authors:  Megan Keener; Farzaneh Fadaei-Tirani; Rosario Scopelliti; Ivica Zivkovic; Marinella Mazzanti
Journal:  Chem Sci       Date:  2022-06-22       Impact factor: 9.969

4.  An Inverted-Sandwich Diuranium μ-η5:η5-Cyclo-P5 Complex Supported by U-P5 δ-Bonding.

Authors:  Benedict M Gardner; Floriana Tuna; Eric J L McInnes; Jonathan McMaster; William Lewis; Alexander J Blake; Stephen T Liddle
Journal:  Angew Chem Weinheim Bergstr Ger       Date:  2015-04-27

5.  Thorium- and uranium-azide reductions: a transient dithorium-nitride versus isolable diuranium-nitrides.

Authors:  Jingzhen Du; David M King; Lucile Chatelain; Erli Lu; Floriana Tuna; Eric J L McInnes; Ashley J Wooles; Laurent Maron; Stephen T Liddle
Journal:  Chem Sci       Date:  2019-02-23       Impact factor: 9.825

6.  An Inverted-Sandwich Diuranium μ-η(5):η(5)-Cyclo-P5 Complex Supported by U-P5 δ-Bonding.

Authors:  Benedict M Gardner; Floriana Tuna; Eric J L McInnes; Jonathan McMaster; William Lewis; Alexander J Blake; Stephen T Liddle
Journal:  Angew Chem Int Ed Engl       Date:  2015-04-27       Impact factor: 15.336
  6 in total

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