Literature DB >> 19585042

Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3).

Velusamy Subbarayan1, Joshua V Ruppel, Shifa Zhu, Jason A Perman, X Peter Zhang.   

Abstract

A Co(II)-based catalytic system has been developed for asymmetric aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3) under mild conditions, forming the corresponding N-Tces-aziridines in high yields and excellent enantioselectivities.

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Year:  2009        PMID： 19585042     DOI： 10.1039/b905727g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  24 in total

1.  Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions.

Authors:  Monalisa Goswami; Volodymyr Lyaskovskyy; Sérgio R Domingos; Wybren Jan Buma; Sander Woutersen; Oliver Troeppner; Ivana Ivanović-Burmazović; Hongjian Lu; Xin Cui; X Peter Zhang; Edward J Reijerse; Serena DeBeer; Matti M van Schooneveld; Florian Felix Pfaff; Kallol Ray; Bas de Bruin
Journal:  J Am Chem Soc       Date:  2015-04-16       Impact factor: 15.419

2.  Asymmetric Induction and Enantiodivergence in Catalytic Radical C-H Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution.

Authors:  Kai Lang; Sebastian Torker; Lukasz Wojtas; X Peter Zhang
Journal:  J Am Chem Soc       Date:  2019-07-29       Impact factor: 15.419

3.  Recent advances in transition metal-catalyzed N-atom transfer reactions of azides.

Authors:  Tom G Driver
Journal:  Org Biomol Chem       Date:  2010-07-08       Impact factor: 3.876

4.  Room Temperature Activation of Aryloxysulfonyl Azides by [Co(II)(TPP)] for Selective Radical Aziridination of Alkenes via Metalloradical Catalysis.

Authors:  Velusamy Subbarayan; Li-Mei Jin; Cui Xin; X Peter Zhang
Journal:  Tetrahedron Lett       Date:  2015-06-03       Impact factor: 2.415

5.  Asymmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis.

Authors:  Huiling Jiang; Kai Lang; Hongjian Lu; Lukasz Wojtas; X Peter Zhang
Journal:  J Am Chem Soc       Date:  2017-06-29       Impact factor: 15.419

6.  Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source.

Authors:  Quyen Nguyen; Ke Sun; Tom G Driver
Journal:  J Am Chem Soc       Date:  2012-04-24       Impact factor: 15.419

7.  Effective synthesis of chiral N-fluoroaryl aziridines through enantioselective aziridination of alkenes with fluoroaryl azides.

Authors:  Li-Mei Jin; Xue Xu; Hongjian Lu; Xin Cui; Lukasz Wojtas; X Peter Zhang
Journal:  Angew Chem Int Ed Engl       Date:  2013-04-15       Impact factor: 15.336

8.  Spin-Selective Generation of Triplet Nitrenes: Olefin Aziridination through Visible-Light Photosensitization of Azidoformates.

Authors:  Spencer O Scholz; Elliot P Farney; Sangyun Kim; Desiree M Bates; Tehshik P Yoon
Journal:  Angew Chem Int Ed Engl       Date:  2016-01-06       Impact factor: 15.336

9.  Catalytic Radical Process for Enantioselective Amination of C(sp3 )-H Bonds.

Authors:  Chaoqun Li; Kai Lang; Hongjian Lu; Yang Hu; Xin Cui; Lukasz Wojtas; X Peter Zhang
Journal:  Angew Chem Int Ed Engl       Date:  2018-11-16       Impact factor: 15.336

Review 10.  Catalytic Enantioselective Functionalization of Unactivated Terminal Alkenes.

Authors:  John R Coombs; James P Morken
Journal:  Angew Chem Int Ed Engl       Date:  2016-01-13       Impact factor: 15.336
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