Literature DB >> 19585019

Substituent-dependent exchange mechanisms in highly fluxional RSn9(3-) anions.

F Sanem Kocak1, Peter Y Zavalij, Yiu-Fai Lam, Bryan W Eichhorn.   

Abstract

119Sn NMR studies show that the RSn9(3-) ions (R=i-Pr, Sn(C6H11)3) are highly fluxional in solution, where the exchange mechanisms involve rapid migration of the R group in the latter but not in the former.

Entities:  

Year:  2009        PMID： 19585019     DOI： 10.1039/b905239a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Synthesis of nine-atom deltahedral Zintl ions of germanium and their functionalization with organic groups.

Authors:  Miriam M Gillett-Kunnath; Slavi C Sevov
Journal:  J Vis Exp       Date:  2012-02-11       Impact factor: 1.355

2.  Isolation and Versatile Derivatization of an Unsaturated Anionic Silicon Cluster (Siliconoid).

Authors:  Philipp Willmes; Kinga Leszczyńska; Yannic Heider; Kai Abersfelder; Michael Zimmer; Volker Huch; David Scheschkewitz
Journal:  Angew Chem Int Ed Engl       Date:  2016-01-22       Impact factor: 15.336
  2 in total

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