Literature DB >> 19569691

Complexation of nitrous oxide by frustrated Lewis pairs.

Edwin Otten1, Rebecca C Neu, Douglas W Stephan.   

Abstract

Frustrated Lewis pairs comprised of a basic yet sterically encumbered phosphine with boron Lewis acids bind nitrous oxide to give intact PNNOB linkages. The synthesis, structure, and bonding of these species are described.

Entities:  

Year:  2009        PMID： 19569691     DOI： 10.1021/ja904377v

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  13 in total

1.  Halogenated triphenylgallium and -indium in frustrated Lewis pair activations and hydrogenation catalysis.

Authors:  Maotong Xu; Josephine Possart; Alexander E Waked; Julie Roy; Werner Uhl; Douglas W Stephan
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2017-08-28       Impact factor: 4.226

Review 2.  Binding and activation of N2O at transition-metal centers: recent mechanistic insights.

Authors:  William B Tolman
Journal:  Angew Chem Int Ed Engl       Date:  2010-02-01       Impact factor: 15.336

3.  Main-group elements as transition metals.

Authors:  Philip P Power
Journal:  Nature       Date:  2010-01-14       Impact factor: 49.962

4.  Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide.

Authors:  Nathaniel J Hartmann; Guang Wu; Trevor W Hayton
Journal:  Angew Chem Int Ed Engl       Date:  2015-10-12       Impact factor: 15.336

5.  Functionalization of Complexed N2O in Bis(pentamethylcyclopentadienyl) Systems of Zirconium and Titanium.

Authors:  Daniel J Mindiola; Lori A Watson; Karsten Meyer; Gregory L Hillhouse
Journal:  Organometallics       Date:  2014-05-22       Impact factor: 3.876

6.  Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3-Induced C-H Functionalizations.

Authors:  Marina Uzelac; Alan R Kennedy; Eva Hevia
Journal:  Inorg Chem       Date:  2017-05-09       Impact factor: 5.165

7.  Heterolytic Si-H Bond Cleavage at a Molybdenum-Oxido-Based Lewis Pair.

Authors:  Niklas Zwettler; Simon P Walg; Ferdinand Belaj; Nadia C Mösch-Zanetti
Journal:  Chemistry       Date:  2018-04-27       Impact factor: 5.236

8.  Tri-insertion with dearomatization of terminal arylalkynes using a carborane based frustrated Lewis pair template.

Authors:  Jian Zhang; Zuowei Xie
Journal:  Chem Sci       Date:  2020-11-28       Impact factor: 9.825

9.  A Highly Reactive Geminal P/B Frustrated Lewis Pair: Expanding the Scope to C-X (X=Cl, Br) Bond Activation.

Authors:  Kamil Samigullin; Isabelle Georg; Michael Bolte; Hans-Wolfram Lerner; Matthias Wagner
Journal:  Chemistry       Date:  2016-02-02       Impact factor: 5.236

10.  Single Electron Transfer to Diazomethane-Borane Adducts Prompts C-H Bond Activations.

Authors:  Levy L Cao; Jiliang Zhou; Zheng-Wang Qu; Douglas W Stephan
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-30       Impact factor: 15.336
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