Literature DB >> 19568616

Boryl ligands and their roles in metal-catalysed borylation reactions.

Li Dang1, Zhenyang Lin, Todd B Marder.   

Abstract

In this feature article, we discuss selected recent aspects of metal boryl (M-BR2) chemistry pertaining, in particular, to the role of late and post-transition metal boryl complexes in various catalytic processes. The exceptionally strong sigma-donor properties of boryl ligands and their related nucleophilic behaviour are highlighted.

Entities:  

Year:  2009        PMID： 19568616     DOI： 10.1039/b903098k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  24 in total

1.  Synthesis of Ruthenium Boryl Analogues of the Shvo Metal-Ligand Bifunctional Catalyst.

Authors:  Liza Koren-Selfridge; Ian P Query; Joel A Hanson; Nicholas A Isley; Ilia A Guzei; Timothy B Clark
Journal:  Organometallics       Date:  2010       Impact factor: 3.876

2.  Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents.

Authors:  Britt A Vanchura; Sean M Preshlock; Philipp C Roosen; Venkata A Kallepalli; Richard J Staples; Robert E Maleczka; Daniel A Singleton; Milton R Smith
Journal:  Chem Commun (Camb)       Date:  2010-09-20       Impact factor: 6.222

3.  Vicinal diboronates in high enantiomeric purity through tandem site-selective NHC-Cu-catalyzed boron-copper additions to terminal alkynes.

Authors:  Yunmi Lee; Hwanjong Jang; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2009-12-30       Impact factor: 15.419

4.  Synthesis and structures of anionic rhenium polyhydride complexes of boron-hydride ligands and their application in catalysis.

Authors:  Liam J Donnelly; Simon Parsons; Carole A Morrison; Stephen P Thomas; Jason B Love
Journal:  Chem Sci       Date:  2020-09-09       Impact factor: 9.825

5.  A catalytic enantioselective tandem allylation strategy for rapid terpene construction: application to the synthesis of pumilaside aglycon.

Authors:  Grace E Ferris; Kai Hong; Ian A Roundtree; James P Morken
Journal:  J Am Chem Soc       Date:  2013-02-07       Impact factor: 15.419

6.  Catalytic enantioselective one-pot aminoborylation of aldehydes: a strategy for construction of nonracemic α-amino boronates.

Authors:  Kai Hong; James P Morken
Journal:  J Am Chem Soc       Date:  2013-06-13       Impact factor: 15.419

7.  Nickel-Catalyzed Dearomative Arylboration of Indoles: Regioselective Synthesis of C2- and C3-Borylated Indolines.

Authors:  Grace L Trammel; Rositha Kuniyil; Phillip F Crook; Peng Liu; M Kevin Brown
Journal:  J Am Chem Soc       Date:  2021-09-28       Impact factor: 16.383

8.  Enantioselective Generation of Adjacent Stereocenters in a Copper-Catalyzed Three-Component Coupling of Imines, Allenes, and Diboranes.

Authors:  Kay Yeung; Rebecca E Ruscoe; James Rae; Alexander P Pulis; David J Procter
Journal:  Angew Chem Int Ed Engl       Date:  2016-08-19       Impact factor: 15.336

9.  Mechanistic Insights into Carbonyl-Directed Rhodium-Catalyzed Hydroboration: ab Initio Study of a Cyclic γ,δ-Unsaturated Amide.

Authors:  Zhao-Di Yang; Rhitankar Pal; Gia L Hoang; Xiao Cheng Zeng; James M Takacs
Journal:  ACS Catal       Date:  2014-01-22       Impact factor: 13.084

10.  (BB)-Carboryne Complex of Ruthenium: Synthesis by Double B-H Activation at a Single Metal Center.

Authors:  Bennett J Eleazer; Mark D Smith; Alexey A Popov; Dmitry V Peryshkov
Journal:  J Am Chem Soc       Date:  2016-08-16       Impact factor: 15.419
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.