| Literature DB >> 19565077 |
C André Ohlin1, Robin Brimblecombe, Leone Spiccia, William H Casey.
Abstract
The rate and activation parameters for oxygen exchange of the mu(3)-oxo bridges in a manganese tetranuclear cluster with H(2)(18)O have been measured by ESI-MS; the observed DeltaS(double dagger) of -146 +/- 22 J K(-1.)mol(-1) is consistent with the expected associative mechanism of substitution.Entities:
Year: 2009 PMID： 19565077 DOI： 10.1039/b906169j
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390