Literature DB >> 19557274

Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Hückel aromatic-antiaromatic interconversion.

Harapriya Rath1, Naoki Aratani, Jong Min Lim, Jae Seok Lee, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka.   

Abstract

Metalation of [28]hexaphyrin(1.1.1.1.1.1) with [RhCl(CO)(2)](2) resulted in the formation of an antiaromatic bis-Rh(i) complex, which can be oxidized to an aromatic bis-Rh(i) complex with retention of its rectangular structure.

Entities:  

Year:  2009        PMID： 19557274     DOI： 10.1039/b905859a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Reversal of Hückel (anti)aromaticity in the lowest triplet states of hexaphyrins and spectroscopic evidence for Baird's rule.

Authors:  Young Mo Sung; Min-Chul Yoon; Jong Min Lim; Harapriya Rath; Koji Naoda; Atsuhiro Osuka; Dongho Kim
Journal:  Nat Chem       Date:  2015-04-13       Impact factor: 24.427

2.  Aromaticity: A light-switched yin and yang pair.

Authors:  Henrik Ottosson; K Eszter Borbas
Journal:  Nat Chem       Date:  2015-05       Impact factor: 24.427

3.  Reversible π-system switching of thiophene-fused thiahexaphyrins by solvent and oxidation/reduction.

Authors:  Tomohiro Higashino; Atsushi Kumagai; Shigeyoshi Sakaki; Hiroshi Imahori
Journal:  Chem Sci       Date:  2018-08-14       Impact factor: 9.825

4.  Synthesis and Characterization of a Binuclear Copper(II)-dipyriamethyrin Complex: [Cu2(dipyriamethyrin)(μ2-1,1-acetato)2].

Authors:  James T Brewster; Harrison D Root; Hadiqa Zafar; Gregory D Thiabaud; Adam C Sedgwick; Jiaming He; Vincent M Lynch; Jonathan L Sessler
Journal:  Molecules       Date:  2020-03-23       Impact factor: 4.411
  4 in total

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