Literature DB >> 19552452

Stabilization of imidosamarium(III) cubane by amidinates.

Cheng-Ling Pan1, Wan Chen, Shuyan Song, Hongjie Zhang, Xingwei Li.   

Abstract

An imidosamarium(III) cubane has been prepared from the reductive cleavage of azobenzene by a divalent samarium bis(amidinate) complex, indicating that the "spectrator" bis(amidinate) and the resulting imido ligands help to stabilize the cubane framework. The cubane-type imido cluster is a novel unit in lanthanide chemistry.

Entities:  

Year:  2009        PMID: 19552452     DOI: 10.1021/ic900808f

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  1 in total

Review 1.  Ligands with Two Monoanionic N,N-Binding Sites: Synthesis and Coordination Chemistry.

Authors:  Robert Kretschmer
Journal:  Chemistry       Date:  2019-11-22       Impact factor: 5.236

  1 in total

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