Literature DB >> 19532940

Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes.

Javier Ruiz1, Bernabé F Perandones.   

Abstract

Oxazole and thiazole molecules N-coordinated to manganese(i) are transformed into their corresponding 2,3-dihydrooxazol-2-ylidene and 2,3-dihydrothiazol-2-ylidene carbene tautomers by acid-base reactions, and subsequently transmetalated to gold(i), via isolable heterometallic intermediates.

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Year:  2009        PMID: 19532940     DOI: 10.1039/b900955h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Antibacterial Thiamine inspired silver (I) and gold (I) N-heterocyclic carbene compounds.

Authors:  Orhi Esarte Palomero; Ashley L Cunningham; Bryan W Davies; Richard A Jones
Journal:  Inorganica Chim Acta       Date:  2020-11-27       Impact factor: 2.545

  1 in total

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