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Literature DB >> 19532938

Stereoselective and controlled polymerization of D,L-lactide using indium(III) trichloride.

Agostino Pietrangelo¹, Marc A Hillmyer, William B Tolman.

Abstract

Indium trichloride, benzyl alcohol, and triethylamine (without an added 'directing' multidentate ligand) generate a catalyst in situ for the room temperature polymerization of D,L-lactide affording highly heterotactic polylactide of controlled molecular weight and narrow molecular weight distribution.

Entities: Chemical

Year: 2009 PMID： 19532938 DOI： 10.1039/b902968k

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

4 in total

1. Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide.

Authors: Srinivas Abbina; Guodong Du
Journal: ACS Macro Lett Date: 2014-07-02 Impact factor: 6.903

2. 8-Quinolinolato gallium complexes: iso-selective initiators for rac-lactide polymerization.

Authors: Clare Bakewell; Andrew J P White; Nicholas J Long; Charlotte K Williams
Journal: Inorg Chem Date: 2013-10-18 Impact factor: 5.165

3. Ring-Opening Polymerization of rac-Lactide with Aluminum Chiral Anilido-Oxazolinate Complexes.

Authors: Shi Bian; Srinivas Abbina; Zhengliang Lu; Edward Kolodka; Guodong Du
Journal: Organometallics Date: 2014-05-09 Impact factor: 3.876

4. Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization.

Authors: D C Aluthge; J M Ahn; P Mehrkhodavandi
Journal: Chem Sci Date: 2015-07-06 Impact factor: 9.825

4 in total