Literature DB >> 19527001

A highly enantioselective allylic amination reaction using a commercially available chiral rhodium catalyst: resolution of racemic allylic carbonates.

Derek C Vrieze1, Garrett S Hoge, Perrine Z Hoerter, Jared T Van Haitsma, Brian M Samas.   

Abstract

A novel method for the kinetic resolution of unsymmetrical acyclic allylic carbonates and the concurrent synthesis of enantioenriched secondary amines using a commercially available chiral catalyst is disclosed.

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Year:  2009        PMID： 19527001     DOI： 10.1021/ol901031b

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  Rhodium-Catalyzed Enantioselective Hydroamination of Alkynes with Indolines.

Authors:  Qing-An Chen; Zhiwei Chen; Vy M Dong
Journal:  J Am Chem Soc       Date:  2015-06-29       Impact factor: 15.419

2.  Amphiphilic π-Allyliridium C,O-Benzoates Enable Regio- and Enantioselective Amination of Branched Allylic Acetates Bearing Linear Alkyl Groups.

Authors:  Arismel Tena Meza; Thomas Wurm; Lewis Smith; Seung Wook Kim; Jason R Zbieg; Craig E Stivala; Michael J Krische
Journal:  J Am Chem Soc       Date:  2018-01-19       Impact factor: 15.419

Review 3.  Alkynes as Electrophilic or Nucleophilic Allylmetal Precursors in Transition-Metal Catalysis.

Authors:  Alexander M Haydl; Bernhard Breit; Tao Liang; Michael J Krische
Journal:  Angew Chem Int Ed Engl       Date:  2017-08-10       Impact factor: 15.336

4.  Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates.

Authors:  Levi M Stanley; Chen Bai; Mitsuhiro Ueda; John F Hartwig
Journal:  J Am Chem Soc       Date:  2010-07-07       Impact factor: 15.419

5.  Enzymatic N-Allylation of Primary and Secondary Amines Using Renewable Cinnamic Acids Enabled by Bacterial Reductive Aminases.

Authors:  Godwin A Aleku; Gabriel R Titchiner; George W Roberts; Sasha R Derrington; James R Marshall; Florian Hollfelder; Nicholas J Turner; David Leys
Journal:  ACS Sustain Chem Eng       Date:  2022-05-06       Impact factor: 9.224
  5 in total

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