| Literature DB >> 19526473 |
Olivier Coulembier1, Daniel P Sanders, Alshakim Nelson, Andrew N Hollenbeck, Hans W Horn, Julia E Rice, Masaki Fujiwara, Philippe Dubois, James L Hedrick.
Abstract
Recognize this! A hydrogen-bonding motif based on hexafluorinated alcohol derivatives (see picture; O red, F yellow) activates electrophilic substrates. The catalytic activity of the hydrogen-bonded systems was demonstrated for the ring-opening polymerization of a variety of strained heterocycles. Narrowly dispersed polymers with predictable molecular weights were obtained with end-group fidelity.Entities:
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Year: 2009 PMID: 19526473 DOI: 10.1002/anie.200901006
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336