| Literature DB >> 19526472 |
Serena Fantasia1, Jonathan D Egbert, Václav Jurcík, Catherine S J Cazin, Heiko Jacobsen, Luigi Cavallo, D Michael Heinekey, Steven P Nolan.
Abstract
An even split: In sharp contrast with the general behavior of Pd(0) complexes, [Pd(IPr)(PCy(3))] is able to activate the H-H bond. The resulting trans-[Pd(H)(2)(IPr)(PCy(3))] is the first isolated mononuclear dihydride palladium compound. Its formation is supported by multinuclear NMR spectroscopy, density functional calculations, and X-ray diffraction studies. The stability and reactivity of this new species are examined.Entities:
Year: 2009 PMID： 19526472 DOI： 10.1002/anie.200900463
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336