Literature DB >> 19507838

A flexible radical-based approach to TMS-substituted propargyl alcohols and to 2,3-allenols.

Zhi Li1, Samir Z Zard.   

Abstract

The radical reaction of TMS-substituted xanthates with 2,2-dichlorovinyl ethyl sulfone afforded TMS-substituted homodichlorovinyl compounds that can be transformed into TMS-substituted propargyl alcohols. Various 2,3-allenols were efficiently prepared from the reaction of these TMS-substituted propargyl alcohols with TBAF.

Entities:  

Year:  2009        PMID: 19507838     DOI: 10.1021/ol900739x

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

Review 1.  Some aspects of radical cascade and relay reactions.

Authors:  Béatrice Quiclet-Sire; Samir Z Zard
Journal:  Proc Math Phys Eng Sci       Date:  2017-04-05       Impact factor: 2.704

2.  Some aspects of radical chemistry in the assembly of complex molecular architectures.

Authors:  Béatrice Quiclet-Sire; Samir Z Zard
Journal:  Beilstein J Org Chem       Date:  2013-03-18       Impact factor: 2.883

  2 in total

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