| Literature DB >> 19505146 |
Lomig Hamon1, Christian Serre, Thomas Devic, Thierry Loiseau, Franck Millange, Gérard Férey, Guy De Weireld.
Abstract
Hydrogen sulfide gravimetric isotherm adsorption measurements were carried out on MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) metal-organic frameworks (MOFs). A two-step adsorption mechanism related to a breathing effect was observed for MIL-53 terephthalate-based MOFs. Methane adsorption measurements highlighted the regenerability of MIL-53(Al, Cr) and MIL-47(V) MOFs after H(2)S treatment, whereas MIL-100 and MIL-101 CH(4) adsorption capacities were significantly decreased.Entities:
Year: 2009 PMID: 19505146 DOI: 10.1021/ja901587t
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419