Literature DB >> 19505127

Design of bicyclic and cage boron compounds based on allylboration of acetylenes with allyldichloroboranes.

Sergey Yu Erdyakov1, Anatolii V Ignatenko, Tamara V Potapova, Konstantin A Lyssenko, Mikhail E Gurskii, Yuri N Bubnov.   

Abstract

Allylboration of acetylenes with allyldichloroboranes has been proposed as a first step of allylboron-acetylene condensation and a way to design condensation products from stage to stage. The chemistry has been applied to the synthesis of isomeric 3-borabicyclo[3.3.1]non-6-enes transformed into 3-methyl-1-boraadamantane and [5-D]-3-methyl-1-boraadamantane derivatives.

Entities:  

Year:  2009        PMID: 19505127     DOI: 10.1021/ol900793r

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  A free boratriptycene-type Lewis superacid.

Authors:  Marcel Henkelmann; Andreas Omlor; Michael Bolte; Volker Schünemann; Hans-Wolfram Lerner; Jozef Noga; Peter Hrobárik; Matthias Wagner
Journal:  Chem Sci       Date:  2021-12-07       Impact factor: 9.825

  1 in total

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