Literature DB >> 19504510

Germanium(II) dications stabilized by azamacrocycles and crown ethers.

Fei Cheng1, Andrew L Hector, William Levason, Gillian Reid, Michael Webster, Wenjian Zhang.   

Abstract

A crown for germanium: Neutral aza- and oxamacrocycles enable stabilization of halide-free germanium(II) dications (see structure, Ge teal, N blue, C gray). The resulting structures show a marked dependence upon the denticity, donor type, and ring size of the macrocycle.

Entities:  

Year:  2009        PMID： 19504510     DOI： 10.1002/anie.200901247

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Reactive p-block cations stabilized by weakly coordinating anions.

Authors:  Tobias A Engesser; Martin R Lichtenthaler; Mario Schleep; Ingo Krossing
Journal:  Chem Soc Rev       Date:  2015-11-27       Impact factor: 54.564

2.  Stepwise isolation of low-valent, low-coordinate Sn and Pb mono- and dications in the coordination sphere of platinum.

Authors:  Holger Braunschweig; Mehmet Ali Celik; Rian D Dewhurst; Magdalena Heid; Florian Hupp; Sakya S Sen
Journal:  Chem Sci       Date:  2014-10-15       Impact factor: 9.825

3.  Halometallate complexes of germanium(II) and (IV): probing the role of cation, oxidation state and halide on the structural and electrochemical properties.

Authors:  Philip N Bartlett; Charles Y Cummings; William Levason; David Pugh; Gillian Reid
Journal:  Chemistry       Date:  2014-03-18       Impact factor: 5.236
  3 in total

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