| Literature DB >> 19496092 |
Imren Hatay1, Bin Su, Fei Li, Raheleh Partovi-Nia, Heron Vrubel, Xile Hu, Mustafa Ersoz, Hubert H Girault.
Abstract
Blowing bubbles: Hydrogen evolution by proton reduction with [(C(5)Me(5))(2)Fe] occurs at a soft interface between water and 1,2-dichloroethane (DCE). The reaction proceeds by proton transfer assisted by [(C(5)Me(5))(2)Fe] across the water-DCE interface with subsequent proton reduction in DCE. The interface essentially acts as a proton pump, allowing hydrogen evolution by directly using the aqueous proton.Entities:
Year: 2009 PMID: 19496092 DOI: 10.1002/anie.200901757
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336