Literature DB >> 19488440

A [Cu(16)S(10)](4-) cluster containing mu(3)- and mu(4)-sulfido ligands.

Lei Yang1, Zhaodong Wang, Douglas R Powell, Robert P Houser.   

Abstract

An anionic, "naked" copper sulfide cluster, [Cu(16)S(10)](4-), was synthesized by treating multi-copper starting materials with the hydrosulfide salt, (nBu(4)N)SH. The sixteen copper atoms in [Cu(16)S(10)](4-) are arranged in a square gyrobicupola with eight mu(3)- and two mu(4)-sulfido ligands.

Entities:  

Year:  2009        PMID： 19488440     DOI： 10.1039/b905375a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  2 in total

1.  Synthesis, structure, and reactions of a copper-sulfido cluster comprised of the parent Cu2S unit: {(NHC)Cu}2(μ-S).

Authors:  Junjie Zhai; Alexander S Filatov; Gregory L Hillhouse; Michael D Hopkins
Journal:  Chem Sci       Date:  2015-10-20       Impact factor: 9.825

2.  Crystal structure of di-μ-hydroxido-bis{[N,N'-bis-(2,6-di-methyl-phen-yl)pentane-2,4-diiminato(1-)]zinc}.

Authors:  Joshua A Goodner; Brandon J Powers; Douglas R Powell; Lei Yang
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-08-06
  2 in total

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