Literature DB >> 19485368

Terminal alkyne activation by frustrated and classical Lewis acid/phosphine pairs.

Meghan A Dureen1, Douglas W Stephan.   

Abstract

Frustrated and classical Lewis pairs arising from combinations of Lewis acids and phosphines react with terminal alkynes either via C-H activation forming an alkynylborate salt or by addition to alkyne giving a zwitterionic phosphonium borate.

Year:  2009        PMID: 19485368     DOI: 10.1021/ja903650w

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  21 in total

1.  Halogenated triphenylgallium and -indium in frustrated Lewis pair activations and hydrogenation catalysis.

Authors:  Maotong Xu; Josephine Possart; Alexander E Waked; Julie Roy; Werner Uhl; Douglas W Stephan
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2017-08-28       Impact factor: 4.226

2.  A DFT study of hydrogen and methane activation by B(C6F5)3/P(t-Bu)3 and Al(C6F5)3/P(t-Bu)3 frustrated Lewis pairs.

Authors:  Nery Villegas-Escobar; Alejandro Toro-Labbé; Marcos Becerra; Misael Real-Enriquez; Jose R Mora; Luis Rincon
Journal:  J Mol Model       Date:  2017-07-21       Impact factor: 1.810

3.  A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes.

Authors:  Konstantin Chernichenko; Adám Madarász; Imre Pápai; Martin Nieger; Markku Leskelä; Timo Repo
Journal:  Nat Chem       Date:  2013-07-07       Impact factor: 24.427

4.  Carbon dioxide reduction by an Al-O-P frustrated Lewis pair.

Authors:  Lucas Wickemeyer; Niklas Aders; Andreas Mix; Beate Neumann; Hans-Georg Stammler; Jorge J Cabrera-Trujillo; Israel Fernández; Norbert W Mitzel
Journal:  Chem Sci       Date:  2022-06-02       Impact factor: 9.969

5.  Direct Conversion of N-Alkylamines to N-Propargylamines through C-H Activation Promoted by Lewis Acid/Organocopper Catalysis: Application to Late-Stage Functionalization of Bioactive Molecules.

Authors:  Jessica Z Chan; Ahmet Yesilcimen; Min Cao; Yuyang Zhang; Bochao Zhang; Masayuki Wasa
Journal:  J Am Chem Soc       Date:  2020-09-11       Impact factor: 15.419

6.  Haloboration of internal alkynes with boronium and borenium cations as a route to tetrasubstituted alkenes.

Authors:  James R Lawson; Ewan R Clark; Ian A Cade; Sophia A Solomon; Michael J Ingleson
Journal:  Angew Chem Int Ed Engl       Date:  2013-06-05       Impact factor: 15.336

7.  Dehydration in water: frustrated Lewis pairs directly catalyzed allylization of electron-rich arenes and allyl alcohols.

Authors:  Hua Zhang; Xiao-Yu Zhan; Yu Dong; Jian Yang; Shuai He; Zhi-Chuan Shi; Xiao-Mei Zhang; Ji-Yu Wang
Journal:  RSC Adv       Date:  2020-04-30       Impact factor: 4.036

8.  Frustrated Lewis Pair Mediated 1,2-Hydrocarbation of Alkynes.

Authors:  Valerio Fasano; Liam D Curless; James E Radcliffe; Michael J Ingleson
Journal:  Angew Chem Int Ed Engl       Date:  2017-07-04       Impact factor: 15.336

9.  Tri-insertion with dearomatization of terminal arylalkynes using a carborane based frustrated Lewis pair template.

Authors:  Jian Zhang; Zuowei Xie
Journal:  Chem Sci       Date:  2020-11-28       Impact factor: 9.825

10.  Metal-ligand multiple bonds as frustrated Lewis pairs for C-H functionalization.

Authors:  Matthew T Whited
Journal:  Beilstein J Org Chem       Date:  2012-09-18       Impact factor: 2.883

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