| Literature DB >> 19480417 |
Takeshi Murata1, Masayuki Sano, Hiroyoshi Takamura, Isao Kadota, Daisuke Uemura.
Abstract
Stereoselective synthesis of the C23-C34 fragment of symbiodinolide, which possesses the originally proposed stereochemistry, and its diastereomers was achieved in 19 steps from L-aspartic acid, respectively. Comparison of spectroscopic data of the synthetic products with those of the degraded product of symbiodinolide led to a structural revision of the C23-C34 fragment.Entities:
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Year: 2009 PMID： 19480417 DOI： 10.1021/jo900546k
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354