Literature DB >> 19479924

Controlled iterative cross-coupling: on the way to the automation of organic synthesis.

Congyang Wang1, Frank Glorius.   

Abstract

Repetition does not hurt! New strategies for the modulation of the reactivity of difunctional building blocks are discussed, allowing the palladium-catalyzed controlled iterative cross-coupling and, thus, the efficient formation of complex molecules of defined size and structure (see scheme). As in peptide synthesis, this development will enable the automation of these reactions. M(PG)=protected metal, M(act)=metal.

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Year:  2009        PMID： 19479924     DOI： 10.1002/anie.200901680

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  13 in total

1.  1,2-Azaborine's Distinct Electronic Structure Unlocks Two New Regioisomeric Building Blocks via Resolution Chemistry.

Authors:  Cameron R McConnell; Fredrik Haeffner; Andrew W Baggett; Shih-Yuan Liu
Journal:  J Am Chem Soc       Date:  2019-05-23       Impact factor: 15.419

2.  From synthesis to function via iterative assembly of N-methyliminodiacetic acid boronate building blocks.

Authors:  Junqi Li; Anthony S Grillo; Martin D Burke
Journal:  Acc Chem Res       Date:  2015-07-22       Impact factor: 22.384

3.  A simple and general platform for generating stereochemically complex polyene frameworks by iterative cross-coupling.

Authors:  Suk Joong Lee; Thomas M Anderson; Martin D Burke
Journal:  Angew Chem Int Ed Engl       Date:  2010-11-15       Impact factor: 15.336

4.  A general solution for the 2-pyridyl problem.

Authors:  Graham R Dick; Eric M Woerly; Martin D Burke
Journal:  Angew Chem Int Ed Engl       Date:  2012-01-27       Impact factor: 15.336

5.  Total synthesis of synechoxanthin through iterative cross-coupling.

Authors:  Seiko Fujii; Stephanie Y Chang; Martin D Burke
Journal:  Angew Chem Int Ed Engl       Date:  2011-06-16       Impact factor: 15.336

Review 6.  Bioinspired iterative synthesis of polyketides.

Authors:  Kuan Zheng; Changmin Xie; Ran Hong
Journal:  Front Chem       Date:  2015-05-21       Impact factor: 5.221

7.  Boryl (Hetero)aryne Precursors as Versatile Arylation Reagents: Synthesis through C-H Activation and Orthogonal Reactivity.

Authors:  Emilien Demory; Karthik Devaraj; Andreas Orthaber; Paul J Gates; Lukasz T Pilarski
Journal:  Angew Chem Int Ed Engl       Date:  2015-08-13       Impact factor: 15.336

8.  Short Enantioselective Total Synthesis of Tatanan A and 3-epi-Tatanan A Using Assembly-Line Synthesis.

Authors:  Adam Noble; Stefan Roesner; Varinder K Aggarwal
Journal:  Angew Chem Int Ed Engl       Date:  2016-11-16       Impact factor: 15.336

9.  The Synthesis of Conjugated Bis-Aryl Vinyl Substrates and Their Photoelectrocyclization Reactions towards Phenanthrene Derivatives.

Authors:  Xuchen Zhao; Jon D Rainier
Journal:  Synthesis (Stuttg)       Date:  2021-01-11       Impact factor: 3.157

10.  Assembly-line synthesis of organic molecules with tailored shapes.

Authors:  Matthew Burns; Stéphanie Essafi; Jessica R Bame; Stephanie P Bull; Matthew P Webster; Sébastien Balieu; James W Dale; Craig P Butts; Jeremy N Harvey; Varinder K Aggarwal
Journal:  Nature       Date:  2014-09-11       Impact factor: 49.962
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