| Literature DB >> 19479912 |
Manuel Ojeda1, Enrique Iglesia.
Abstract
Selective HCOOH decomposition to H(2)/CO(2) on Au: Au species catalyze HCOOH dehydrogenation at higher rates than on Pt, previously considered the most active metal. Dehydrogenation occurs through formate decomposition limited by H(2) desorption on Au species undetectable by TEM. CO did not form (<10 ppm), making products suitable for low-temperature fuel cells.Entities:
Year: 2009 PMID: 19479912 DOI: 10.1002/anie.200805723
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336