Literature DB >> 19479892

A direct route to bifunctional aldehyde derivatives via self- and cross-metathesis of unsaturated aldehydes.

Xiaowei Miao1, Cédric Fischmeister, Christian Bruneau, Pierre H Dixneuf.   

Abstract

Ruthenium-catalyzed self- and cross-metathesis, with acrolein, acrylonitrile, acrylic acid and methylacrylate, of the bioresource undecylenic aldehyde leads to a variety of unsaturated omega-functional aldehydes. Tandem olefin metathesis/hydrogenation catalytic reactions afford saturated C(20) and C(12) diols in good yields.

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Year:  2009        PMID： 19479892     DOI： 10.1002/cssc.200900028

Source DB:  PubMed          Journal:  ChemSusChem        ISSN： 1864-5631            Impact factor:   8.928


  4 in total

1.  About the activity and selectivity of less well-known metathesis catalysts during ADMET polymerizations.

Authors:  Hatice Mutlu; Lucas Montero de Espinosa; Oĝuz Türünç; Michael A R Meier
Journal:  Beilstein J Org Chem       Date:  2010-12-03       Impact factor: 2.883

2.  The cross-metathesis of methyl oleate with cis-2-butene-1,4-diyl diacetate and the influence of protecting groups.

Authors:  Arno Behr; Jessica Pérez Gomes
Journal:  Beilstein J Org Chem       Date:  2011-01-03       Impact factor: 2.883

3.  Olefin cross metathesis based de novo synthesis of a partially protected L-amicetose and a fully protected L-cinerulose derivative.

Authors:  Bernd Schmidt; Sylvia Hauke
Journal:  Beilstein J Org Chem       Date:  2014-05-06       Impact factor: 2.883

4.  Cross metathesis of unsaturated epoxides for the synthesis of polyfunctional building blocks.

Authors:  Meriem K Abderrezak; Kristýna Šichová; Nancy Dominguez-Boblett; Antoine Dupé; Zahia Kabouche; Christian Bruneau; Cédric Fischmeister
Journal:  Beilstein J Org Chem       Date:  2015-10-08       Impact factor: 2.883
  4 in total

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