| Literature DB >> 19449888 |
Jocelyn G Millar1, Jardel A Moreira, J Steven McElfresh, Kent M Daane, Amy S Freund.
Abstract
The sex pheromone of the longtailed mealybug, identified as 2-(1,5,5-trimethylcyclopent-2-en-1-yl)ethyl acetate, represents the first example of a new monoterpenoid skeleton. A [2,3]-sigmatropic rearrangement was used in a key step during construction of the sterically congested tetraalkylcylopentene framework.Entities:
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Year: 2009 PMID： 19449888 DOI： 10.1021/ol802164v
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005